Physical Properties Of Alkyl Halides - The Very Fact Issue

- Amongst isomeric alkyl halides, the boiling level decreases with the rise in branching in the alkyl group, because with branching the molecule attains spherical form with much less surface area. Consequently, interparticle forces become weaker. Hence the boiling point decreases. The order of boiling level is Main > Secondary >= iso > Tertiary

- Therefore boiling level of neo-pentyl chloride
Bromomethane, Bromoform, Chloromethane, Dibromomethane:

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- Kim J., Z. Dohnalek, J.M. White, and B.D. Kay. 2004. "Reactive Progress of Nanoscale MgO Films by Mg Atom Deposition onto O2 Multilayers." Journal of Physical Chemistry B 108, no. 31:11666-11671. PNNL-SA-40944.

- Liu S., Z. Dohnalek, R.S. Smith, and B.D. Kay. 2004. "Interplay of CH4, CH3Cl, CH2CI2, and CCl4 with O-terminated FeO(111)." Journal of Physical Chemistry B 108, no. 11:3644-3650. PNNL-SA-39787.


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